Search results for "Silver trifluoromethanesulfonate"

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C,N-chelated organotin(IV) trifluoromethanesulfonates: Synthesis, characterization and preliminary studies of its catalytic activity in the direct sy…

2012

Abstract C,N-chelated tri- and diorganotin(IV) halides react with 1 or 2 mol equiv of silver trifluoromethanesulfonate (triflate, AgOTf, OTf = OSO2CF3−) to give corresponding C,N-chelated organotin(IV) triflates. The triorganotin(IV) triflates of general formula LCNR2SnOTf (R = n-Bu (1), Ph (2)) are presumably more stable towards hydrolysis than the diorganotin(IV) triflates LCNRSn(OTf)2 (R = n-Bu (3), Ph (4)). All prepared organotin(IV) triflates bearing the LCN ligand (where LCN is 2-(N,N-dimethylaminomethyl)phenyl-) were characterized by multinuclear NMR spectroscopy and elemental analysis. In addition, the structure of 3 was determined by the X-ray diffraction analysis. The catalytic ac…

LigandOrganic ChemistryNuclear magnetic resonance spectroscopyBiochemistryMedicinal chemistryCatalysisInorganic Chemistrychemistry.chemical_compoundHydrolysischemistryMaterials ChemistryOrganic chemistrySilver trifluoromethanesulfonateMethanolPhysical and Theoretical ChemistryDimethyl carbonateTrifluoromethanesulfonateJournal of Organometallic Chemistry
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CCDC 1823431: Experimental Crystal Structure Determination

2018

Related Article: Rajendhraprasad Tatikonda, Evgeny Bulatov, Zülal Özdemir, Nonappa, Matti Haukka|2019|Soft Matter|15|442|doi:10.1039/C8SM02006J

Space GroupCrystallographyCrystal Systemcatena-(bis(mu-N-(pyridin-3-yl)pyridine-4-carboxamide)-silver trifluoromethanesulfonate)Crystal StructureCell ParametersExperimental 3D Coordinates
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